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On their practical circumstances

In fact as much as 10% of glucose consumption, by erythrocytes, may be mediated by the pentose phosphate pathway

The lyophilised form is inherently more stable than reconstituted solution because water is absent, eliminating the primary degradation pathway (hydrolysis)

Impurity profiling quality control testing of synthetic peptides using liquid chromatography-photodiode array-fluorescence and liquid chromatography-electrospray ionization-mass spectrometry: The obestatin case. Analytical Biochemistry

Gressier B

In order to distinguish them from the normal organic reactions, such chemical reactions are sometimes referred to as anti-Markownikoff or Kharasch mechanisms