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kinetic control 1,4-addition products tend to be more thermodynamically stable since they involve breaking a C-C pi bond (60 kcal/mol) instead of a C-O pi bond (80 kcal/mol)

10.1016/j.biopha.2018.04.175 251 ZhaoW.LuoH.LinZ.HuangL.PanZ.ChenL.et al (2024)

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Patients often ask about why colchicine, which has been available in unbranded form for many years, is now a branded drug (Colcrys, Mitigare)